Spin-lattice NMR relaxation by anomalous translational diffusion.
نویسندگان
چکیده
A model-free theoretical framework for a phenomenological description of spin-lattice relaxation by anomalous translational diffusion in inhomogeneous systems based on the fractional diffusion equation is developed. The dependence of the spin-lattice relaxation time on the size of the pores in porous glass Vycor is experimentally obtained and found to agree well with our theoretical predictions. We obtain nonmonotonic behavior of the translational spin-lattice relaxation rate constant (it passes through a maximum) with the variation of the parameter referring to the extent of inhomogeneity of the system.
منابع مشابه
0 Fe b 20 04 Spin - lattice NMR relaxation by anomalous translational diffusion
A model-free theoretical framework for phenomenological description of spinlattice relaxation by anomalous translational diffusion in inhomogeneous systems based on the fractional diffusion equation is developed. The dependence of the spin-lattice relaxation time on the size of the pores in porous glass Vycor is experimentally obtained and found to agree well with theoretical predictions. We ob...
متن کاملnd - m at . s of t ] 2 1 D ec 2 00 4 Spin - lattice NMR relaxation by anomalous translational diffusion
A model-free theoretical framework for a phenomenological description of spinlattice relaxation by anomalous translational diffusion in inhomogeneous systems based on the fractional diffusion equation is developed. The dependence of the spinlattice relaxation time on the size of the pores in porous glass Vycor is experimentally obtained and found to agree well with our theoretical predictions. ...
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ورودعنوان ژورنال:
- Journal of magnetic resonance
دوره 172 1 شماره
صفحات -
تاریخ انتشار 2005